Outbound rules dictate how 3CX routes outgoing calls, i.e. via different SIP trunks or gateways, based on which user or group is calling, the dialled number or the number length. You need to create at least one outbound rule to start calling with 3CX. Sometimes you will find 3CX creates an outbound route automatically if it is the only route your 3CX installation has.
To create an outbound call rule in the Management Console and route calls via this trunk: